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Архив | Том 25, 2020, No. 3.

РЕАКЦИЯ [2+4]-ЦИКЛОПРИСОЕДИНЕНИЯ 2-МЕРКАПТОЭТАНОЛА К ФУЛЛЕРЕНУ С60 В ПРИСУТСТВИИ NAH ПОД ДЕЙСТВИЕМ УЛЬТРАЗВУКА

Вестник Башкирского университета. 2020. Том 25. №3. С. 506-511.
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DOI: https://doi.org/10.33184/bulletin-bsu-2020.3.7

  • © З. С. Кинзябаева

    Институт нефтехимии и катализа УФИЦ РАН

    Россия, Республика Башкортостан, 450075 Уфа, пр. Октября, 141

  • © А. М. Дмитриев

    Башкирский государственный университет

    Россия, Республика Башкортостан, 450076 г. Уфа, ул. Заки Валиди, 32

В реакции фуллерена С60 с 2-меркаптоэтанолом в присутствии NaH под действием ультразвука получен ранее неизвестный 1,4-оксатиановый аддукт фуллерена. Полученное соединение идентифицировано с использованием масс-(MALDI TOF/TOF), одно- и двумерной ЯМР 1Н, 13С (COSY, HSQC, HMBS), УФ-видимой спектроскопией.

Ключевые слова:

  • фуллерен С60
  • 1
  • 2-гидрокситиолы
  • ультразвук
  • гетероциклические соединения
  • fullerene С60
  • 1,2-hydroxythiols
  • ultrasound
  • heterocyclic compounds

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